4-[3-(2H-Benzotriazol-2-yl)propoxy]-3-methoxybenzaldehyde
نویسندگان
چکیده
In the title compound, C(17)H(17)N(3)O(3), the 3-methoxy-benzalde-hyde group and the benzotriazole fragment are connected through a flexible oxypropyl chain. The O-C-C-C torsion angle in the central link is -63.9 (2)°, while the plane of the benzene ring of the 3-methoxy-benzaldehyde substituent forms a dihedral angle of 56.4 (4)° with the benzotriazole plane.
منابع مشابه
Bis[2-(2H-benzotriazol-2-yl)-4-methylphenolato]palladium(II)
In the title complex, [Pd(C(13)H(10)N(3)O)(2)], the Pd(II) atom is tetra-coordinated by two N atoms and two O atoms from two bidentate 2-(2H-benzotriazol-2-yl)-4-methylphenolate ligands, forming a square-planar environment. The asymmetric unit contains one half mol-ecule in which the Pd atom lies on a centre of symmetry.
متن کامل2-(2H-Benzotriazol-2-yl)-4-methylphenyl diphenylphosphinate
In the title mol-ecule, C(25)H(20)N(3)O(2)P, the dihedral angle between the mean planes of the benzotriazol ring system and the N-bonded benzene ring is 45.8 (2)°. All but one of the angles at the P atom show slight distortions from an ideal tetra-hedral geometry.
متن کاملBis(μ-trimethylsilanolato-κ2 O:O)bis{[2-(2H-benzotriazol-2-yl)-4,6-di-tert-pentylphenolato-κ2 N,O]zinc}
The binuclear title complex, [Zn(2)(C(22)H(28)N(3)O)(2)(C(3)H(9)OSi)(2)], has a crystallographic imposed centre of symmetry. The Zn(II) atom is coordinated by three O and one N atom from one 2-(2H-benzotriazol-2-yl)-4,6-di-tert-pentyl-phenolate ligand and two bridging trimethyl-silanolate anions in a distorted tetra-hedral geometry. The dihedral angle between the benzotriazole ring system and t...
متن کاملSynthesis, characterization and reactivity of single-site aluminium amides bearing benzotriazole phenoxide ligands: catalysis for ring-opening polymerization of lactide and carbon dioxide/propylene oxide coupling.
New aluminium complexes containing bis-BTP ligands (BTP = N,O-bidentate benzotriazole phenoxide) were synthesized and structurally characterized. Amine elimination of Al(NMe2)3 with (R)BTP-H ligands ((CMe2Ph)BTP-H = 2-(2H-benzotriazol-2-yl)-4,6-bis(1-methyl-1-phenylethyl)phenol, (t-Bu)BTP-H = 2-(2H-benzotriazol-2-yl)-4,6-di-tert-butylphenol and (TMCl)BTP-H = 2-tert-butyl-6-(5-chloro-2H-benzotri...
متن کامل3-(2H-Benzotriazol-2-yl)-1-(4-fluorophenyl)propan-1-one
In the title compound, C(15)H(12)FN(3)O, the benzotriazole ring system is essentially planar, with a maximum deviation from the least-squares plane of 0.016 (3) Å. The dihedral angle between this ring system and the fluoro-substituted benzene ring is 67.97 (2)°. The crystal structure is stabilized by weak inter-molecular C-H⋯N inter-actions.
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عنوان ژورنال:
دوره 66 شماره
صفحات -
تاریخ انتشار 2010